Self-activation and activation of Cu(0) wire for SET-LRP mediated by fluorinated alcohols-Reference-Cited by-同舟云学术

Self-activation and activation of Cu(0) wire for SET-LRP mediated by fluorinated alcohols

Published:2014 Issue:1 Volume:5 Page:89-95
ISSN:1759-9954
Container-title:Polymer Chemistry
language:en
Short-container-title:Polym. Chem.

Author:

Samanta Shampa R.¹²³⁴⁵,Sun Hao-Jan¹²³⁴⁵,Anastasaki Athina¹²³⁴⁵,Haddleton David M.²⁶⁷⁸,Percec Virgil¹²³⁴⁵

Affiliation:

1. Roy & Diana Vagelos Laboratories

2. Department of Chemistry

3. University of Pennsylvania

4. Philadelphia

5. USA

6. University of Warwick

7. Coventry

8. UK

Abstract

Herein we report the self-activation and activation of Cu(0) wire used to form a catalyst in single-electron transfer living radical polymerization (SET-LRP) in two fluorinated alcohols employed as solvents, 2,2,2-trifluoroethanol (TFE) and 2,2,3,3-tetrafluoropropanol (TFP).

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

Link

http://pubs.rsc.org/en/content/articlepdf/2014/PY/C3PY01007D

Reference77 articles.

1. Single-Electron Transfer and Single-Electron Transfer Degenerative Chain Transfer Living Radical Polymerization

2. Aqueous Room Temperature Metal-Catalyzed Living Radical Polymerization of Vinyl Chloride

3. Ultrafast Synthesis of Ultrahigh Molar Mass Polymers by Metal-Catalyzed Living Radical Polymerization of Acrylates, Methacrylates, and Vinyl Chloride Mediated by SET at 25 °C

4. Living radical polymerization of vinyl chloride initiated with iodoform and catalyzed by nascent Cu0/tris(2-aminoethyl)amine or polyethyleneimine in water at 25 °C proceeds by a new competing pathways mechanism

5. SET-LRP of vinyl chloride initiated with CHBr3 and catalyzed by Cu(0)-wire/TREN in DMSO at 25 °C

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