Ni(<scp>ii</scp>)-catalyzed oxidative deamination of benzyl amines with water-Reference-Cited by-同舟云学术

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Ni(ii)-catalyzed oxidative deamination of benzyl amines with water

Published:2023 Issue:16 Volume:25 Page:6212-6217
ISSN:1463-9262
Container-title:Green Chemistry
language:en
Short-container-title:Green Chem.

Author:

Pal Nilay Kumar¹^ORCID,Singh Kuldeep¹,Patra Moumita¹,Yadav Suman¹,Pandey Prabhakar K.¹,Bera Jitendra K.¹^ORCID

Affiliation:

1. Department of Chemistry and Centre for Environmental Sciences and Engineering, Indian Institute of Technology Kanpur, Kanpur 208016, India

Abstract

A sulfonate-functionalized water-soluble Ni(ii)–NHC catalyst is utilized for the oxidative deamination of benzyl amines, wherein water acts as a formal oxidant to give an aldehyde, which is then converted to useful products.

Funder

Science and Engineering Research Board

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/GC/D3GC00672G

Reference64 articles.

1. S. A.Lawrence , Amines: Synthesis Properties and Applications , Cambridge University Press , Oxford , 2004

2. Aliphatic deaminations in organic synthesis

3. R. J.Baumgarten and V. A.Curtis , Deaminations (carbon–nitrogen bond cleavages) in Amino, Nitroso and Nitro Compounds and Their Derivatives , John Wiley & Sons Ltd , New York , 1982

4. Self-sustaining closed-loop multienzyme-mediated conversion of amines into alcohols in continuous reactions

5. Oxidation of primary, secondary, and tertiary amines with neutral permanganate. Simple method for degrading amines to aldehydes and ketones

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