Regioselective oxidation of unprotected 1,4 linked glucans-Reference-Cited by-同舟云学术

Regioselective oxidation of unprotected 1,4 linked glucans

Published:2016 Issue:21 Volume:14 Page:4859-4864
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Eisink Niek N. H. M.¹²³⁴,Lohse Jonas¹²³⁴,Witte Martin D.¹²³⁴,Minnaard Adriaan J.¹²³⁴

Affiliation:

1. Stratingh Institute for Chemistry

2. University of Groningen

3. 9747 AG Groningen

4. The Netherlands

Abstract

Palladium-catalyzed alcohol oxidation allows the chemo- and regioselective modification of unprotected 1,4 linked glucans, shown here for 3-keto heptamaltoside azide.

Funder

Nederlandse Organisatie voor Wetenschappelijk Onderzoek

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/OB/C6OB00608F

Reference23 articles.

1. O–H hydrogen bonding promotes H-atom transfer from α C–H bonds for C-alkylation of alcohols

2. Regioselective modification of unprotected glycosides

3. An Approach to the Site-Selective Deoxygenation of Hydroxy Groups Based on Catalytic Phosphoramidite Transfer

4. δ-Galactonolactone: Synthesis, Isolation, and Comparative Structure and Stability Analysis of an Elusive Sugar Derivative

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