The p-sc structure in phosphorus: bringing order to the high pressure phases of group 15 elements

Author:

Scelta Demetrio12345ORCID,Baldassarre Adhara67458ORCID,Serrano-Ruiz Manuel12345ORCID,Dziubek Kamil6745ORCID,Cairns Andrew B.9101112ORCID,Peruzzini Maurizio12345ORCID,Bini Roberto12345ORCID,Ceppatelli Matteo12345ORCID

Affiliation:

1. CNR-ICCOM

2. Institute of Chemistry of OrganoMetallic Compounds

3. National Research Council of Italy

4. I-50019 Sesto Fiorentino (FI)

5. Italy

6. LENS

7. European Laboratory for Non-linear Spectroscopy

8. Università degli Studi di Firenze

9. ESRF

10. European Synchrotron Radiation Facility

11. 38000 Grenoble

12. France

Abstract

High pressure state-of-the-art synchrotron XRD in black-phosphorus has solved apparent contradictions about the stability of the A7 layered structure in pnictogens, highlighting the importance of the s–p orbital mixing in the formation of the p-sc structure.

Funder

H2020 European Research Council

Ministero dell'Istruzione, dell'Università e della Ricerca

Ente Cassa di Risparmio di Firenze

Alfred P. Sloan Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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