Expedient synthesis and ring-opening metathesis polymerization of pyridinonorbornenes-Reference-Cited by-同舟云学术

Expedient synthesis and ring-opening metathesis polymerization of pyridinonorbornenes

Published:2022 Issue:39 Volume:13 Page:5530-5535
ISSN:1759-9954
Container-title:Polymer Chemistry
language:en
Short-container-title:Polym. Chem.

Author:

Hancock Sarah N.¹^ORCID,Yuntawattana Nattawut¹,Valdez Sara M.¹,Michaudel Quentin¹²^ORCID

Affiliation:

1. Department of Chemistry, Texas A&M University, College Station, Texas 77843, USA

2. Department of Materials Science and Engineering, Texas A&M University, College Station, Texas 77843, USA

Abstract

Pyridinonorbornenes, a unique family of ROMP monomers, were synthesized via the intermediacy of 2,3-pyridynes. Modulation of the steric hindrance about the nitrogen allowed a living ROMP process and the production of polymers with high Tg and Td.

Funder

Texas A and M University

Welch Foundation

National Institute of General Medical Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

Link

http://pubs.rsc.org/en/content/articlepdf/2022/PY/D2PY00857B

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