The missing pieces of the PuO2 nanoparticle puzzle

Author:

Gerber Evgeny12345ORCID,Romanchuk Anna Yu.6789ORCID,Pidchenko Ivan12345ORCID,Amidani Lucia12345ORCID,Rossberg Andre12345,Hennig Christoph12345ORCID,Vaughan Gavin B. M.1023ORCID,Trigub Alexander11129,Egorova Tolganay6789ORCID,Bauters Stephen12345ORCID,Plakhova Tatiana6789ORCID,Hunault Myrtille O. J. Y.1314153ORCID,Weiss Stephan451617ORCID,Butorin Sergei M.1819202122ORCID,Scheinost Andreas C.12345ORCID,Kalmykov Stepan N.678911ORCID,Kvashnina Kristina O.12345ORCID

Affiliation:

1. The Rossendorf Beamline at ESRF – The European Synchrotron

2. 38043 Grenoble Cedex 9

3. France

4. Helmholtz-Zentrum Dresden-Rossendorf (HZDR)

5. Institute of Resource Ecology

6. Lomonosov Moscow State University

7. Department of Chemistry

8. 119991 Moscow

9. Russia

10. ESRF – The European Synchrotron

11. National Research Centre “Kurchatov Institute”

12. 123182 Moscow

13. Synchrotron SOLEIL

14. L'Orme des Merisiers

15. 91192 Gif-sur-Yvette

16. Dresden

17. Germany

18. Molecular and Condensed Matter Physics

19. Department of Physics and Astronomy

20. Uppsala University

21. Uppsala

22. Sweden

Abstract

We report a full characterization of PuO2 nanoparticles at the atomic level and probe their local and electronic structure by a variety of methods available at the synchrotron and theoretical approaches.

Funder

H2020 European Research Council

Russian Foundation for Basic Research

Ministry of Education and Science of the Russian Federation

Vetenskapsrådet

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science

Reference76 articles.

1. Theatre: Atomic tragedian

2. D. Albright , S.Kelleher-Vergantini and D.Schnur

3. Identification of the Formal +2 Oxidation State of Plutonium: Synthesis and Characterization of {PuII[C5H3(SiMe3)2]3}−

4. J. J. Katz , G. T.Seaborg and L. R.Morss , The chemistry of the actinide elements , Chapman and Hall , London , 1986

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