Synthesis of the large pore aluminophosphate STA-1 and its application as a catalyst for the Beckmann rearrangement of cyclohexanone oxime-Reference-Cited by-同舟云学术

Synthesis of the large pore aluminophosphate STA-1 and its application as a catalyst for the Beckmann rearrangement of cyclohexanone oxime

Published:2024 Issue:25 Volume:12 Page:15398-15411
ISSN:2050-7488
Container-title:Journal of Materials Chemistry A
language:en
Short-container-title:J. Mater. Chem. A

Author:

González-Camuñas Nuria¹²^ORCID,Cantín Ángel¹^ORCID,Dawson Daniel M.³^ORCID,Lozinska Magdalena M.³,Martínez-Triguero Joaquín¹^ORCID,Mattock James⁴,Cox Paul A.⁴^ORCID,Ashbrook Sharon E.³^ORCID,Wright Paul A.³^ORCID,Rey Fernando¹^ORCID

Affiliation:

1. Instituto de Tecnología Química (ITQ), Universitat Politècnica de València (UPV) – Consejo Superior de Investigaciones Científicas (CSIC), 46022 Valencia, Spain

2. Instituto de Tecnología Cerámica, Universidad Jaume I, Campus Universitario Riu Sec, Avda. Vicente Sos Baynat s/n, 12006, Castellón, Spain

3. EaStCHEM School of Chemistry, University of St Andrews, Purdie Building, St Andrews, KY16 9ST, UK

4. School of Pharmacy and Biomedical Sciences, University of Portsmouth, Portsmouth, PO1 2DT, UK

Abstract

Microporous AlPO4 STA-1 has been synthesised and studied by NMR crystallography; it is an effective catalyst for the Beckmann rearrangement of cyclohexanone oxime.

Funder

Generalitat Valenciana

Ministerio de Ciencia e Innovación

Engineering and Physical Sciences Research Council

Biotechnology and Biological Sciences Research Council

University of Warwick

Advantage West Midlands

University of St Andrews

European Regional Development Fund

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/TA/D4TA01132E

Reference68 articles.

1. Aluminophosphate molecular sieves: a new class of microporous crystalline inorganic solids

2. R.Szostak , Synthesis of Molecular Sieve Phosphates , in Synthesis , Springer , Berlin, Heidelberg , 2001 , vol. 1 , pp. 157–185

3. Structural, Synthetic and Physicochemical Concepts in Aluminophosphate-Based Molecular Sieves

4. Silicoaluminophosphate molecular sieves: another new class of microporous crystalline inorganic solids