Ab initio insights into the mechanism of excited-state intramolecular proton transfer triggered by the second excited singlet state of a fluorescent dye: an anti-Kasha behavior
Author:
Affiliation:
1. Institute of Upconversion Nanoscale Materials
2. Henan Provincial Engineering Research Center of Green Anticorrosion Technology for Magnesium Alloy
3. College of Chemistry and Chemical Engineering
4. Henan University
5. Kaifeng 475004
Abstract
An excited-state intramolecular proton transfer (ESIPT) reaction triggered by the second excited singlet S2 state is found by ab initio calculations to be an ultrafast process for a novel fluorophore.
Funder
National Natural Science Foundation of China
Publisher
Royal Society of Chemistry (RSC)
Subject
Materials Chemistry,General Materials Science
Link
http://pubs.rsc.org/en/content/articlepdf/2019/QM/C9QM00179D
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5. Fine Tuning the Energetics of Excited-State Intramolecular Proton Transfer (ESIPT): White Light Generation in A Single ESIPT System
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