Syntheses and evaluation of new hydrophilic azacryptands used as masking agents of technetium in solvent extraction processes
Author:
Affiliation:
1. CEA
2. DES
3. ISEC
4. DMRC
5. University of Montpellier
6. Dipartimento di Chimica
7. Università di Pavia
8. I-27100 Pavia
9. Italy
10. INSTM
Abstract
New azacryptands with the addition of hydrophilic groups were synthesized to bind selectively the pertechnetate anion in nitric acid medium, and avoid its extraction in the separation process.
Funder
Électricité de France
Commissariat à l'Énergie Atomique et aux Énergies Alternatives
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2021/DT/D0DT04210B
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3. Technetium chemistry, oxidation states and species
4. The behavior of technetium in technetium-scrubbing stage of PUREX process
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