Copper-catalyzed asymmetric silyl addition to alkenyl-substituted N-heteroarenes-Reference-Cited by-同舟云学术

Copper-catalyzed asymmetric silyl addition to alkenyl-substituted N-heteroarenes

Published:2020 Issue:11 Volume:56 Page:1693-1696
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Zeng Ya-Li¹²³⁴⁵,Chen Bo¹²³⁴⁵,Wang Ya-Ting¹²³⁴⁵,He Cheng-Yu¹²³⁴⁵,Mu Zi-Yuan¹²³⁴⁵,Du Ji-Yuan³⁶⁷⁸^ORCID,He Long⁹¹⁰¹¹⁸,Chu Wen-Dao¹²³⁴⁵^ORCID,Liu Quan-Zhong¹²³⁴⁵

Affiliation:

1. Chemical Synthesis and Pollution Control

2. Key Laboratory of Sichuan Province

3. College of Chemistry and Chemical Engineering

4. China West Normal University

5. Nanchong 637002

6. Liaocheng University

7. Liaocheng

8. China

9. College of Chemistry and Materials Engineering

10. Guiyang University

11. Guiyang 550005

Abstract

Asymmetric conjugate addition of PhMe₂SiBPin to a wide range of N-heteroaryl alkenes proceeded in the presence of a copper catalyst coordinated with a chiral phosphoramidite ligand to afford useful β-silyl N-heteroarenes in high yields and ees.

Funder

National Natural Science Foundation of China

Department of Science and Technology of Sichuan Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CC/C9CC08910A

Reference69 articles.

1. C═N-Containing Azaarenes as Activating Groups in Enantioselective Catalysis

2. Conjugate Additions to Vinyl-Substituted Aromatic N-Heterocycles

3. Aromatic Heterocycles as Activating Groups for Asymmetric Conjugate Addition Reactions. Enantioselective Copper-Catalyzed Reduction of 2-Alkenylheteroarenes

4. Enantioselective Rhodium-Catalyzed Addition of Arylboronic Acids to Alkenylheteroarenes

5. Enantioselective rhodium-catalyzed arylation of electron-deficient alkenylarenes

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