Formation of n → π+ interaction facilitating dissociative electron transfer in isolated tyrosine-containing molecular peptide radical cations

Author:

Tang Wai Kit12345,Mu Xiaoyan16758,Li Mengzhu1675,Martens Jonathan910111213ORCID,Berden Giel910111213ORCID,Oomens Jos910111213ORCID,Chu Ivan K.1675ORCID,Siu Chi-Kit12345ORCID

Affiliation:

1. Department of Chemistry

2. City University of Hong Kong

3. Tat Chee Avenue

4. Kowloon Tong

5. China

6. The University of Hong Kong

7. Pokfulam

8. College of Chemistry

9. Radboud University

10. Institute for Molecules and Materials

11. FELIX Laboratory

12. Toernooiveld 7

13. 6525 ED Nijmegen

Abstract

IRMPD suggests existence of π-radicals of [FYGG]˙+ featuring the n → π+ interaction, which are reactive intermediates toward dissociative electron transfer.

Funder

Research Grants Council, University Grants Committee

National Natural Science Foundation of China

Natural Science Foundation of Shandong Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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