Palladium-catalysed directed remote <i>meta</i>-C–H functionalization of arenes using a cyclopentenyl-pyridyl template-Reference-Cited by-同舟云学术

Palladium-catalysed directed remote meta-C–H functionalization of arenes using a cyclopentenyl-pyridyl template

Published:2024 Issue:34 Volume:48 Page:15172-15178
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Huang Jun¹,Tang Jinghong¹,Yan Yifei²,Liu Zelin¹,He Siquan¹,Jin Zhong¹²^ORCID

Affiliation:

1. Key Laboratory of Xinjiang Native Medicinal and Edible Plant Resource Chemistry, College of Chemistry and Environmental Sciences, Kashi University, Kashgar 844000, China

2. College of Chemistry, National Engineering Research Center of Pesticide, State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin 300071, China

Abstract

Highly meta-selective C–H olefination, deuteration and acetoxylation of benzyl alcohols were realized by applying a practical directing template featuring a non-aromatic cyclopentenyl-pyridine scaffold.

Funder

National Natural Science Foundation of China

National Key Research and Development Program of China

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/NJ/D4NJ02945C

Reference58 articles.

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2. Palladium-catalysed norbornene-mediated C–H functionalization of arenes

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4. Access to the meta position of arenes through transition metal catalysed C–H bond functionalisation: a focus on metals other than palladium

5. Advancing the Logic of Chemical Synthesis: C−H Activation as Strategic and Tactical Disconnections for C−C Bond Construction