Synthesis of model bacteriochlorophylls containing substituents of native rings A, C and E
Author:
Affiliation:
1. Department of Chemistry
2. North Carolina State University
3. Raleigh
4. USA
Abstract
An established route to the bacteriochlorophyll skeleton from two dihydrodipyrrin halves has been extended to accommodate several substituents characteristic of the native bacteriochlorophyll a.
Funder
National Science Foundation
Publisher
Royal Society of Chemistry (RSC)
Subject
Materials Chemistry,General Chemistry,Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2021/NJ/D1NJ02469H
Reference51 articles.
1. H. Scheer , in Chlorophylls and Bacteriochlorophylls. Biochemistry, Biophysics, Functions and Applications , ed. B. Grimm , R. J. Porra , W. Rüdiger and H. Scheer , Springer , Dordrecht, The Netherlands , 2006 , vol. 25, pp. 1–26
2. Total synthesis campaigns toward chlorophylls and related natural hydroporphyrins – diverse macrocycles, unrealized opportunities
3. Construction of the Bacteriochlorin Macrocycle with Concomitant Nazarov Cyclization To Form the Annulated Isocyclic Ring: Analogues of Bacteriochlorophyll a
4. Asymmetric Synthesis of a Bacteriochlorophyll Model Compound Containing trans-Dialkyl Substituents in Ring D
5. De Novo Synthesis of Gem-Dialkyl Chlorophyll Analogues for Probing and Emulating Our Green World
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