Water exchange reaction of a manganese catalase mimic: oxygen-17 NMR relaxometry study on (aqua)manganese(iii) in a salen scaffold and its reactions in a mildly basic medium-Reference-Cited by-同舟云学术

Water exchange reaction of a manganese catalase mimic: oxygen-17 NMR relaxometry study on (aqua)manganese(iii) in a salen scaffold and its reactions in a mildly basic medium

Published:2016 Issue:113 Volume:6 Page:111739-111746
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Mundlapati V. Rao¹²³⁴⁵,Jena Priyambada⁶⁷⁸⁵,Acharya Achyut N.⁶⁷⁸⁵,Kar Akshaya K.⁶⁹¹⁰⁵,Dash Anadi C.⁶⁹¹⁰⁵,Biswal Himansu S.¹²³⁴⁵

Affiliation:

1. School of Chemical Sciences

2. National Institute of Science Education and Research (NISER)

3. Institute of Physics Campus

4. Bhubaneswar 751 005

5. India

6. Department of Chemistry

7. College of Engineering and Technology

8. Bhubaneswar 751003

9. Utkal University

10. Bhubaneswar 751004

Abstract

Water exchange of trans-[Mn^III(salen)(OH₂)₂]⁺ studied by line broadening ¹⁷OH₂ NMR discloses its mechanism as associative interchange (I_a).

Funder

University Grants Commission

Science and Engineering Research Board

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/RA/C6RA23154C

Reference50 articles.

1. Ligand substitution and electron transfer reactions of trans-(diaqua)(salen)manganese(iii) with oxalate: an experimental and computational study

2. Kinetics and mechanism of the reaction of sulphur(IV) with N,N?-ethylene-bis(sali-cylidiniminato)manganese-(III) in aqueous solution

3. Glyoxylate as a reducing agent for manganese(III) in salen scaffold: A kinetics and mechanistic study

4. (Salen)Mn(III) Compound as a Nonpeptidyl Mimic of Catalase: DFT Study of the Metal Oxidation by a Peroxide Molecule

5. (salen)MnIII Compounds as Nonpeptidyl Mimics of Catalase. Mechanism-Based Tuning of Catalase Activity: A Theoretical Study

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