A2Zn3P4S13 (A = Rb and Cs): First Infrared Nonlinear Optical Materials with Mixed Thiophosphate Functional Motifs PS4 and P2S6-Reference-Cited by-同舟云学术

A₂Zn₃P₄S₁₃ (A = Rb and Cs): First Infrared Nonlinear Optical Materials with Mixed Thiophosphate Functional Motifs PS₄ and P₂S₆

Published:2022 Issue:23 Volume:10 Page:9146-9151
ISSN:2050-7526
Container-title:Journal of Materials Chemistry C
language:en
Short-container-title:J. Mater. Chem. C

Author:

Li Ming-Ze¹²,Jiang Lin-Tao¹²,Pei Shao-Min¹,Liu Bin-Wen¹^ORCID,Jiang Xiao-Ming¹^ORCID,Guo Guo-Cong¹^ORCID

Affiliation:

1. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China

2. College of Chemistry, Fuzhou University, Fuzhou, Fujian 350116, P. R. China

Abstract

Two new IR NLO thiophosphates A2Zn3P4S13 (A = Rb, Cs) feature [Zn3P4S13] anionic framework and contain two types of NLO-active thiophosphate units (PS4 and P2S6), which to our best knowledge is unprecedented in known IR NLO thiophosphates.

Funder

Youth Innovation Promotion Association of the Chinese Academy of Sciences

National Natural Science Foundation of China

Natural Science Foundation of Fujian Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/TC/D2TC01351G

Reference48 articles.

1. Rational design of infrared nonlinear optical chalcogenides by chemical substitution