Synthesis of new asymmetric substituted boron amidines – reactions with CO and transfer hydrogenations of phenylacetylene-Reference-Cited by-同舟云学术

Synthesis of new asymmetric substituted boron amidines – reactions with CO and transfer hydrogenations of phenylacetylene

Published:2015 Issue:45 Volume:44 Page:19606-19614
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Cabrera Alan R.¹²³⁴⁵,Rojas Rene S.¹²³⁴⁵,Valderrama Mauricio¹²³⁴⁵,Plüss Pascal⁶⁷⁸⁹,Berke Heinz⁶⁷⁸⁹,Daniliuc Constantin G.¹⁰¹¹¹²¹³,Kehr Gerald¹⁰¹¹¹²¹³,Erker Gerhard¹⁰¹¹¹²¹³

Affiliation:

1. Nucleus Millennium of Chemical Processes and Catalysis

2. Departamento de Química Inorgánica

3. Facultad de Química

4. Pontificia Universidad Católica de Chile

5. Santiago

6. Chemisches Institut

7. Universität Zürich

8. CH-8057 Zürich

9. Switzerland

10. Organisch-Chemisches Institut

11. Westfälische Wilhelms-Universität

12. D-48149 Münster

13. Germany

Abstract

Formation of amidine–BH(C₆F₅)₂adducts and their thermal dehydrogenation, CO uptake to form five-membered cyclic compounds and stoichiometric transfer hydrogenation toward phenylacetylene.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT01966D

Reference52 articles.

1. “Frustrated Lewis pairs”: a concept for new reactivity and catalysis

2. Frustrated Lewis pairs: a new strategy to small molecule activation and hydrogenation catalysis

3. Frustrated Lewis Pairs: Metal-free Hydrogen Activation and More

4. Organometallic frustrated Lewis pair chemistry

5. Frustrated Lewis pairs: Reactions with dihydrogen and other “small molecules”

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