Synthesis and oxidation catalysis of a difluoride-incorporated polyoxovanadate and isolation of active vanadium alkylperoxo species-Reference-Cited by-同舟云学术

Synthesis and oxidation catalysis of a difluoride-incorporated polyoxovanadate and isolation of active vanadium alkylperoxo species

Published:2022 Issue:8 Volume:12 Page:2438-2445
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Kikukawa Yuji¹^ORCID,Sakamoto Yui¹,Hirasawa Hikari¹,Kurimoto Yushi¹,Iwai Hiroya¹,Hayashi Yoshihito¹^ORCID

Affiliation:

1. Department of Chemistry, Graduate School of Natural Science and Technology, Kanazawa University, Kakuma, Kanazawa 920-1192, Japan

Abstract

Haloperoxidase-mimetic peroxo-vanadium species on an inorganic support showed catalytic reactivity for the epoxidation and bromination of alkenes. The structures of both native and peroxo forms were determined via single-crystal X-ray analysis.

Funder

Sumitomo Foundation

Nippon Sheet Glass Foundation for Materials Science and Engineering

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CY/D1CY02103F

Reference71 articles.

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