Mechanistic understanding and the rational design of a SiO<sub>2</sub>@CD catalyst for selective protection of <scp>l</scp>-lysine-Reference-Cited by-同舟云学术

Mechanistic understanding and the rational design of a SiO₂@CD catalyst for selective protection of l-lysine

Published:2023 Issue:3 Volume:21 Page:551-563
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Li Pinyi¹²,Fu Xue¹³,Zhou Qiang¹,Fu Xuewen¹,Wang An³,Zhang Guolin¹,Jiao Wei¹^ORCID,Wang Chun¹^ORCID

Affiliation:

1. Chengdu Institute of Biology, Chinese Academy of Sciences, Chengdu 610041, China

2. University of Chinese Academy of Sciences, Beijing 100049, China

3. College of Architecture and Environment, Sichuan university, Chengdu 610065, China

Abstract

The mechanism of the selective protection of l-lysine mediated by β-cyclodextrin (β-CD) was investigated by preliminary experiments. The existence of (1a·CD)′ and 1a·CD·2a was proved to be critical for the selectivity and catalytic efficiency.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/OB/D2OB01535H

Reference32 articles.

1. High-efficiency dynamic sensing of biothiols in cancer cells with a fluorescent β-cyclodextrin supramolecular assembly

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3. Cyclodextrin Porous Liquid Materials for Efficient Chiral Recognition and Separation of Nucleosides

4. Enhanced adsorption of naproxen from aquatic environments by β-cyclodextrin-immobilized reduced graphene oxide

5. Cyclodextrin Cavity-Induced Mechanistic Switch in Copper-Catalyzed Hydroboration