Centrosymmetric K2SO4·(SbF3)2 and noncentrosymmetric Rb2SO4·(SbF3)2 resulting from cooperative effects of lone pair and cation size-Reference-Cited by-同舟云学术

Centrosymmetric K2SO4·(SbF3)2 and noncentrosymmetric Rb2SO4·(SbF3)2 resulting from cooperative effects of lone pair and cation size

Published:2019 Issue:11 Volume:6 Page:3125-3132
ISSN:2052-1553
Container-title:Inorganic Chemistry Frontiers
language:en
Short-container-title:Inorg. Chem. Front.

Author:

Wang Qian¹²³⁴,Wang Lei¹²³⁴,Zhao Xiaoyu⁵⁶³⁴,Huang Ling¹²³⁴^ORCID,Gao Daojiang¹²³⁴,Bi Jian¹²³⁴,Wang Xin⁵⁶³⁴,Zou Guohong⁵⁶³⁴^ORCID

Affiliation:

1. College of Chemistry and Materials Science

2. Sichuan Normal University

3. Chengdu

4. P. R. China

5. College of Chemistry

6. Sichuan University

Abstract

The cooperative effects of the lone pair and cation size were used to tune the symmetry of two stoichiometrically equivalent compounds, A₂SO₄·(SbF₃)₂ (A = K or Rb).

Funder

National Natural Science Foundation of China

Fundamental Research Funds for the Central Universities

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/QI/C9QI01036J

Reference64 articles.

1. Noncentrosymmetric Oxides

2. Bulk characterization methods for non-centrosymmetric materials: second-harmonic generation, piezoelectricity, pyroelectricity, and ferroelectricity

3. Viewpoint: Inorganic Materials for UV and Deep-UV Nonlinear-Optical Applications

4. Ba2NaClP2O7: Unprecedented Phase Matchability Induced by Symmetry Breaking and Its Unique Fresnoite-Type Structure

5. Rb 3 VO(O 2 ) 2 CO 3 : A Four‐in‐One Carbonatoperoxovanadate Exhibiting an Extremely Strong Second‐Harmonic Generation Response

Cited by 53 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. KSb2F7·2KNO3: Unveiling the peak birefringence in inorganic antimony oxysalts;Chinese Chemical Letters;2024-06

2. Influence of Cation-Size Effects of Alkaline Earth (Ae) Metals on Dimensionality and Optical Anisotropy Regulation in K₄AeP₂S₈ Thiophosphates;Inorganic Chemistry;2024-04-23

3. From ZnF₂ to ZnF₂(H₂O)₄: Partial Substitution Achieves Structural Transformation and Nonlinear Optical Activity while Keeping Short Ultraviolet Cutoff Edge;Inorganic Chemistry;2024-01-17

4. Synthesis and Characterization of Metal Iso-cyamelurate K_0.5In_0.5(H₂C₆N₇O₃)₂·9H₂O with Large Birefringence;Crystal Growth & Design;2024-01-08

5. Crystal clear: unveiling giant birefringence in organic–inorganic cocrystals;Chemical Science;2024