Iron(ii) spin crossover complexes with diaminonaphthalene-based Schiff base-like ligands: 1D coordination polymers

Author:

Lochenie Charles1234,Gebauer Andreas1234,Klimm Ottokar1234,Puchtler Florian5234,Weber Birgit1234

Affiliation:

1. Inorganic Chemistry II

2. Universität Bayreuth

3. 95440 Bayreuth

4. Germany

5. Inorganic Chemistry I

Abstract

Iron(ii) spin crossover coordination polymers with diaminonaphthalene derived Schiff base-like ligands were synthesised, and their magnetic and structural properties were analysed. Rigid bridging ligands having up to 40 K wide hysteresis loops were observed.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Reference61 articles.

1. Spin-Crossover Materials, ed. M. A. Halcrow, John Wiley & Sons Ltd, Chichester, 2013

2. Structure:function relationships in molecular spin-crossover complexes

3. Spin Crossover in Transition Metal Compounds I-III, ed. P. Gütlich and H. Goodwin, Springer Berlin/Heidelberg, 2004, pp. 233–235

4. Molecular spin crossover phenomenon: recent achievements and prospects

5. Thermo-, piezo-, photo- and chemo-switchable spin crossover iron(II)-metallocyanate based coordination polymers

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