Chlorophosphines as auxiliary ligands in ruthenium-catalyzed nitrile hydration reactions: application to the preparation of β-ketoamides

Author:

González-Fernández Rebeca12345,González-Liste Pedro J.12345,Borge Javier62578,Crochet Pascale12345ORCID,Cadierno Victorio12345

Affiliation:

1. Laboratorio de Compuestos Organometálicos y Catálisis (Unidad Asociada al CSIC)

2. Centro de Innovación en Química Avanzada (ORFEO-CINQA)

3. Departamento de Química Orgánica e Inorgánica

4. IUQOEM

5. Universidad de Oviedo

6. Departamento de Química Física y Analítica

7. E-33006 Oviedo

8. Spain

Abstract

The utility of chlorophosphines as auxiliary ligands in metal-catalyzed nitrile hydration reactions has been demonstrated, along with their application in the preparation of β-ketoamides.

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Reference127 articles.

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2. The Amide Linkage: Structural Significance in Chemistry, Biochemistry and Materials Science, ed. A. Greenberg, C. M. Breneman and J. F. Liebman, John Wiley & Sons, New York, 2000

3. Polyesters and Polyamides, ed. B. L. Deopura, B. Gupta, M. Joshi and R. Alagirusami, CRC Press, Boca Raton, 2008

4. A. I. Johansson , in Kirk-Othmer Encyclopedia of Chemical Technology, John Wiley & Sons, New York, 2004, vol. 2, pp. 442–463

5. Methoden Org. Chem. (Houben Weyl), ed. D. Dopp and H. Dopp, Thieme Verlag, Stuttgart, 1985, vol. E52, pp. 1024–1031

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