Hydroamination of carbodiimides, isocyanates, and isothiocyanates by a bis(phosphinoselenoic amide) supported titanium(iv) complex-Reference-Cited by-同舟云学术

Hydroamination of carbodiimides, isocyanates, and isothiocyanates by a bis(phosphinoselenoic amide) supported titanium(iv) complex

Published:2016 Issue:44 Volume:45 Page:17824-17832
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Bhattacharjee Jayeeta¹²³⁴,Das Suman¹²³⁴,Kottalanka Ravi K.¹²³⁴⁵,Panda Tarun K.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. Indian Institute of Technology Hyderabad

3. Kandi, Sangareddy 502285

4. India

5. Department of Science & Humanities

Abstract

A titanium(iv) complex [{Ph₂P(Se)NCH₂–}₂Ti(NMe₂)₂] (1) was synthesized and utilized as competent pre-catalyst for hydroamination of various amines towards carbodiimides, isocyanates, and isothiocyanates under mild conditions (25–60 °C).

Funder

Science and Engineering Research Board

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C6DT03063G

Reference158 articles.

1. Organolanthanide-Catalyzed Intramolecular Hydroamination/Cyclization/Bicyclization of Sterically Encumbered Substrates. Scope, Selectivity, and Catalyst Thermal Stability for Amine-Tethered Unactivated 1,2-Disubstituted Alkenes

2. Organolanthanide constrained geometry complexes modified for catalysis: synthesis, structure, and aminoalkene hydroamination properties of a pyrrolidine-substituted constrained geometry organolutetium complex

3. N,O-Chelating Four-Membered Metallacyclic Titanium(IV) Complexes for Atom-Economic Catalytic Reactions