Scandium and lanthanum hydride complexes stabilized by super-bulky penta-arylcyclopentadienyl ligands-Reference-Cited by-同舟云学术

Scandium and lanthanum hydride complexes stabilized by super-bulky penta-arylcyclopentadienyl ligands

Published:2021 Issue:63 Volume:57 Page:7766-7769
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Wang Yang¹²³⁴⁵^ORCID,Del Rosal Iker⁶⁷⁸⁹¹⁰^ORCID,Qin Guorui¹²³⁴⁵^ORCID,Zhao Lanxiao¹²³⁴⁵^ORCID,Maron Laurent⁶⁷⁸⁹¹⁰^ORCID,Shi Xianghui¹²³⁴⁵^ORCID,Cheng Jianhua¹²³⁴⁵^ORCID

Affiliation:

1. State Key Laboratory of Polymer Physics and Chemistry

2. Changchun Institute of Applied Chemistry

3. Chinese Academy of Sciences

4. Changchun 130022

5. China

6. LPCNO

7. CNRS & INSA

8. UPS

9. Université de Toulouse

10. 31077 Toulouse

Abstract

Bimetallic scandium complex [(Cp^Ar5)Sc(H)(μ-OC₄H₉)]₂ (Cp^Ar5 = C₅Ar₅, Ar = 3,5-ⁱPr₂-C₆H₃) (2) with two terminal hydrido ligands, and lanthanum hydride complex [(Cp^Ar5)La(μ-H)]₂ (4) bearing the reduced Cp^Ar5 ligand were obtained.

Funder

National Natural Science Foundation of China

Grand Équipement National De Calcul Intensif

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CC/D1CC01841H

Reference59 articles.

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2. Novel polymerization catalysts and hydride clusters from rare-earth metal dialkyls

3. Variable nuclearity scorpionate-supported lanthanide polyhydrides: [(TpR,R′)LnH2]n (n=3, 4 and 6)

4. Rare-earth dialkyl and dihydride complexes bearing monoanionic ancillary ligands

5. Molecular Rare-Earth-Metal Hydrides in Non-Cyclopentadienyl Environments

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