A second-order nonlinear optical material with a 5-fold interpenetrating diamondoid framework based on two achiral precursors: spontaneous resolution to absolute chiral induction
Author:
Affiliation:
1. State Key Laboratory of Coordination Chemistry
2. School of Chemistry and Chemical Engineering
3. Collaborative Innovation Center of Advanced Microstructures
4. Nanjing University
5. Nanjing
Abstract
A pair of enantiomeric Zn(ii) complexes have been synthesized through spontaneous resolution. Fortunately, the handedness of bulk crystals can be controlled by using a chiral induction agent. Notably, they display strong SHG response.
Funder
National Natural Science Foundation of China
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT00614D
Reference49 articles.
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