Macrocycle supported dinuclear lanthanide complexes with different β-diketonate co-ligands displaying zero field single-molecule magnetic behaviour

Author:

Pramanik Kuheli12ORCID,Sun Yu-Chen3,Brandão Paula4ORCID,Jana Narayan Ch.2ORCID,Wang Xin-Yi3ORCID,Panja Anangamohan12ORCID

Affiliation:

1. Department of Chemistry, Gokhale Memorial Girls’ College, 1/1 Harish Mukherjee Road, Kolkata, 700020, India

2. Department of Chemistry, Panskura Banamali College, Panskura RS, WB, 721152, India

3. State Key Laboratory of Coordination Chemistry, Collaborative Innovation Center of Advanced Microstructures, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, 210023, China

4. Department of Chemistry, CICECO-Aveiro Institute of Materials, University of Aveiro, 3810-193, Aveiro, Portugal

Abstract

Three different sets of isomorphous dinuclear Gd/Dy complexes with an uncommon macrocyclic ligand and β-diketonate co-ligands were reported in which Dy2 analogues are zero field SMMs.

Funder

Council of Scientific and Industrial Research, India

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

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