Rhodium catalysts with superbulky NHC ligands for the selective α-hydrothiolation of alkynes-Reference-Cited by-同舟云学术

Rhodium catalysts with superbulky NHC ligands for the selective α-hydrothiolation of alkynes

Published:2022 Issue:11 Volume:51 Page:4429-4434
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Bołt Małgorzata¹^ORCID,Delaude Lionel²^ORCID,Żak Patrycja¹^ORCID

Affiliation:

1. Department of Organometallic Chemistry, Faculty of Chemistry, Adam Mickiewicz University in Poznan, Umultowska 89B, 61-614 Poznan, Poland

2. Laboratory of Organometallic Chemistry and Homogeneous Catalysis, Institut de Chimie Organique (B6a), Allée du six août 13, Quartier Agora, Université de Liège, 4000 Liège, Belgium

Abstract

Eight rhodium complexes—including four new compounds—with the generic formula [RhCl(cod)(NHC)] were prepared, characterized, and found to be catalytically active in the hydrothiolation of terminal alkynes with aliphatic or aromatic thiols.

Funder

Narodowe Centrum Nauki

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D2DT00243D

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