Synthesis and structure of a family of rhodium polystannide clusters [Rh@Sn10]3–, [Rh@Sn12]3–, [Rh2@Sn17]6– and the first triply-fused stannide, [Rh3@Sn24]5

Synthesis and structure of a family of rhodium polystannide clusters [Rh@Sn10]3–, [Rh@Sn12]3–, [Rh2@Sn17]6– and the first triply-fused stannide, [Rh3@Sn24]5–

Published:2019 Issue:16 Volume:10 Page:4394-4401
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Liu Chao¹²³⁴⁵,Jin Xiao⁶⁷⁸⁹,Li Lei-Jiao¹⁰¹¹¹²¹³,Xu Jun¹²³⁴⁵^ORCID,McGrady John E.⁶⁷⁸⁹^ORCID,Sun Zhong-Ming¹²³⁴⁵^ORCID

Affiliation:

1. School of Materials Science and Engineering & National Institute for Advanced Materials

2. Tianjin Key Lab for Rare Earth Materials and Applications

3. Center for Rare Earth and Inorganic Functional Materials

4. State Key Laboratory of Elemento-Organic Chemistry

5. Nankai University

6. Department of Chemistry

7. University of Oxford

8. Oxford OX1 3QR

9. UK

10. School of Chemistry & Environmental Engineering

11. Changchun University of Science & Technology

12. Changchun 130022

13. China

Abstract

Triply fused cluster: edge shared of three [Rh@Sn₁₀] subunits lead to the largest endohedral polystannide with an entirely new triply fused topology.

Funder

National Natural Science Foundation of China

People's Government of Jilin Province

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/SC/C8SC03948H

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