Organocatalytic asymmetric desymmetrization of 4,4-disubstituted cyclohexadienones via an intermolecular Diels

Organocatalytic asymmetric desymmetrization of 4,4-disubstituted cyclohexadienones via an intermolecular Diels–Alder reaction

Published:2015 Issue:45 Volume:13 Page:11039-11045
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Takagi Ryukichi¹²³⁴⁵,Nishi Takehiko¹²³⁴⁵

Affiliation:

1. Department of Chemistry

2. Graduate School of Science

3. Hiroshima University

4. Higashi-Hiroshima 739-8526

5. Japan

Abstract

Asymmetric desymmetrization of 4,4-disubstituted cyclohexadienones via a chiral phosphoric acid-catalyzed enantioselective intermolecular Diels–Alder reaction is developed.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/OB/C5OB01760B

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