Dihydrogen bond interactions as a result of H2cleavage at Cu, Ag and Au centres-Reference-Cited by-同舟云学术

Dihydrogen bond interactions as a result of H2cleavage at Cu, Ag and Au centres

Published:2016 Issue:18 Volume:18 Page:12810-12818
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Grabowski Sławomir J.¹²³⁴⁵,Ruipérez Fernando⁶⁷⁸⁹⁴

Affiliation:

1. Faculty of Chemistry

2. University of the Basque Country and Donostia International Physics Center (DIPC)

3. 20080 Donostia-San Sebastián

4. Spain

5. IKERBASQUE

6. POLYMAT

7. University of the Basque Country UPV/EHU

8. Joxe Mari Korta Center

9. 20018 Donostia-San Sebastián

Abstract

Dihydrogen activation at M centres (M = Cu, Ag and Au) of metal fluorides, MF, leads to H₂cleavage and the formation of a dihydrogen bonded complex in the cases of Cu and Ag. For the AuF + H₂reaction, the complex linked through the Au⋯H interaction is formed.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CP/C6CP00046K

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