Anthradithiophene-based organic semiconductors through regiodirected double annulations

Author:

Nitti Andrea12345ORCID,Forti Giacomo12345,Bianchi Gabriele678910,Botta Chiara111213145,Tinti Francesca151216175,Gazzano Massimo151216175ORCID,Camaioni Nadia151216175,Po Riccardo678910ORCID,Pasini Dario12345ORCID

Affiliation:

1. Department of Chemistry and INSTM Research Unit

2. University of Pavia

3. Via Taramelli 12

4. 27100 Pavia

5. Italy

6. Research Center for Renewable Energies and Environment

7. Istituto Donegani

8. Eni Spa

9. Via Fauser 4

10. 28100 Novara

11. Istituto di Scienze e Tecnologie Chimiche ‘G. Natta’ (SCITEC-CNR) and INSTM Research Unit

12. Consiglio Nazionale delle Ricerche (CNR)

13. Via Golgi 19

14. 20133 Milano

15. Istituto per la Sintesi Organica e la Fotoreattività (ISOF-CNR)

16. Via P. Gobetti 101

17. 40129 Bologna

Abstract

An innovative double annulation regiospecific synthesis of angularly fused anthradithiophene-based scaffolds is reported, carried out with very low values for E factors. Further functionalization affords small molecules as semiconducting organic materials.

Funder

Università degli Studi di Pavia

Eni

Ministero dell’Istruzione, dell’Università e della Ricerca

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

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