Mechanistic diversity in acetophenone transfer hydrogenation catalyzed by ruthenium iminophosphonamide complexes
Author:
Affiliation:
1. A.N. Nesmeyanov Institute of Organoelement Compounds
2. Russian Academy of Sciences
3. 119991 Moscow
4. Russia
5. CNRS
6. Laboratoire de Chimie de Coordination
7. Université de Toulouse
8. UPS
9. INPT
Abstract
The electron donating power of the R′ substituents in arene ruthenium iminophosphonamide complexes, [(Arene)RuCl{R2P(NR′)2}] (1), controls the mechanism for the acetophenone transfer hydrogenation in isopropanol.
Funder
Russian Science Foundation
Ministère des Affaires Etrangères
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2020/DT/C9DT04532E
Reference38 articles.
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2. The Golden Age of Transfer Hydrogenation
3. Asymmetric Transfer Hydrogenation in Water with Platinum Group Metal Catalysts
4. Asymmetric Transfer Hydrogenation of Aromatic Ketones Catalyzed by Chiral Ruthenium(II) Complexes
5. Amino alcohol effects on the ruthenium(II)-catalysed asymmetric transfer hydrogenation of ketones in propan-2-ol
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