Secondary diamines as a monomer from bis-hydroaminomethylation of industrial cyclic dienes
Author:
Affiliation:
1. Department of Bio- and Chemical Engineering
2. TU Dortmund
3. 44227 Dortmund
4. Germany
5. Global Technology
6. OXEA Services GmbH
7. 46147 Oberhausen
Abstract
Acetic acid gives amines wings: bis-hydroaminomethylation of dienes to provide industrial secondary diamine monomers. Application of reactive extraction as a recycling method for the rhodium catalyst.
Publisher
Royal Society of Chemistry (RSC)
Subject
Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2017/CY/C7CY01050H
Reference41 articles.
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2. Highly efficient catalytic system for the formation of dialdehydes from dicyclopentadiene hydroformylation
3. Rhodium complex catalyzed hydroformylation reactions of linear and cyclic mono- and diolefins
4. Hydroformylation and hydrocarbonylation of dicyclopentadiene with cobalt—rhodium catalytic systems promoted by triphenylphosphine: Synthesis of monoformyltricyclodecenes, diformyltricyclodecanes and di(tricyclodecenyl)ketones
5. Tertiary Amines as Ligands in a Four-Step Tandem Reaction of Hydroformylation and Hydrogenation: An Alternative Route to Industrial Diol Monomers
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1. Recent Developments on Processes for Recovery of Rhodium Metal from Spent Catalysts;Catalysts;2022-11-11
2. Synthesis of primary amines via linkage of hydroaminomethylation of olefins and splitting of secondary amines;Applied Catalysis A: General;2018-01
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