Ligand and solvent effects on CO<sub>2</sub> insertion into group 10 metal alkyl bonds-Reference-Cited by-同舟云学术

Ligand and solvent effects on CO₂ insertion into group 10 metal alkyl bonds

Published:2022 Issue:8 Volume:13 Page:2391-2404
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Deziel Anthony P.¹,Espinosa Matthew R.¹,Pavlovic Ljiljana²^ORCID,Charboneau David J.¹,Hazari Nilay¹^ORCID,Hopmann Kathrin H.²^ORCID,Mercado Brandon Q.¹

Affiliation:

1. Department of Chemistry, Yale University, P. O. Box 208107, New Haven, Connecticut, 06520, USA

2. Department of Chemistry, UiT The Arctic University of Norway, N-9307 Tromsø, Norway

Abstract

The kinetics of carbon dioxide insertion into a pincer-supported palladium methyl complex are studied. The complex inserts carbon dioxide at room temperature, and we explore both solvent and Lewis acid effects on carbon dioxide insertion.

Funder

National Science Foundation

Norges Forskningsråd

Tromsø Forskningsstiftelse

NordForsk

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/SC/D1SC06346D

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