Preparation of an ion with the highest calculated proton affinity: ortho-diethynylbenzene dianion-Reference-Cited by-同舟云学术

Preparation of an ion with the highest calculated proton affinity: ortho-diethynylbenzene dianion

Published:2016 Issue:9 Volume:7 Page:6245-6250
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Poad Berwyck L. J.¹²³⁴⁵,Reed Nicholas D.⁶⁷⁸⁵,Hansen Christopher S.⁶⁷⁸⁵,Trevitt Adam J.⁶⁷⁸⁵,Blanksby Stephen J.¹²³⁴⁵^ORCID,Mackay Emily G.⁹¹⁰¹¹⁵,Sherburn Michael S.⁹¹⁰¹¹⁵,Chan Bun⁶¹²¹³⁵,Radom Leo⁶¹²¹³⁵

Affiliation:

1. Central Analytical Research Facility

2. Institute for Future Environments

3. Queensland University of Technology

4. Brisbane

5. Australia

6. School of Chemistry

7. University of Wollongong

8. Gwynneville

9. Research School of Chemistry

10. Australian National University

11. Canberra

12. University of Sydney

13. Sydney

Abstract

Owing to the increased proton affinity that results from additional negative charges, multiply-charged anions are shown as a route to preparing powerful ‘superbases’.

Funder

Australian Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/SC/C6SC01726F

Reference26 articles.

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4. Lithium Diisopropylamide: Solution Kinetics and Implications for Organic Synthesis

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