Replacing amine by azide: dopamine azide polymerization triggered by sodium periodate

Author:

Szukowska Monika12,Popenda Łukasz3,Coy Emerson3ORCID,Filip Claudiu4,Grajewski Jakub1ORCID,Kempiński Mateusz5,Kim Yeonho6ORCID,Mrówczyński Radosław12ORCID

Affiliation:

1. Faculty of Chemistry, Adam Mickiewicz University, ul. Uniwersytetu Poznańskiego 8, 61-614 Poznań, Poland

2. Center for Advanced Technologies, ul. Uniwersytetu Poznańskiego 10, 61-614 Poznań, Poland

3. NanoBioMedical Centre, Adam Mickiewicz University, ul. Wszechnicy Piastowskiej 3, 61-614, Poznań, Poland

4. National Institute for R&D of Isotopic and Molecular Technologies, 400293 Cluj, Romania

5. Faculty of Physics, Adam Mickiewicz University, ul. Uniwersytetu Poznańskiego 2, 61-614 Poznań, Poland

6. Department of Applied Chemistry, Konkuk University, Chungju 27478, Republic of Korea

Abstract

We report the polymerization of dopamine analogue 4-(2-azidoethyl)benzene-1,2-diol (dopamine azide), where the amine group is switched to azide, resulting in particles stable in water but, in contrast to other polycatechol based polymers, soluble in organic solvents.

Funder

Narodowe Centrum Nauki

Unitatea Executiva pentru Finantarea Invatamantului Superior, a Cercetarii, Dezvoltarii si Inovarii

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

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