Scandium-catalyzed stereoselective block and alternating copolymerization of diphenylphosphinostyrenes and isoprene-Reference-Cited by-同舟云学术

Scandium-catalyzed stereoselective block and alternating copolymerization of diphenylphosphinostyrenes and isoprene

Published:2022 Issue:23 Volume:13 Page:3498-3505
ISSN:1759-9954
Container-title:Polymer Chemistry
language:en
Short-container-title:Polym. Chem.

Author:

Fu Tingting¹,Jiang Lei¹,Sun Hanyang¹,Hou Zhaomin¹²³^ORCID,Guo Fang¹^ORCID

Affiliation:

1. State Key Laboratory of Fine Chemicals, Department of Polymer Science and Engineering, School of Chemical Engineering, Dalian University of Technology, Dalian 116012, China

2. Organometallic Chemistry Laboratory, RIKEN Cluster for Pioneering Research, 2-1 Hirosawa, Wako, Saitama 351-0198, Japan

3. Advanced Catalysis Research Group, RIKEN Center for Sustainable Resource Science, 2-1 Hirosawa, Wako, Saitama 351-0198, Japan

Abstract

The coordination copolymerization of polar diphenylphosphinostyrenes and isoprene by (C5Me4SiMe3)Sc(CH2C6H4NMe2-o)2 afforded a new series of phosphine-functionalized alternating and block isoprene–styrene copolymers.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

Link

http://pubs.rsc.org/en/content/articlepdf/2022/PY/D2PY00290F

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