Topochemical cross-linking of diacetylene in a highly interpenetrated three-dimensional covalent organic framework

Author:

Liu Shangqing12,Chen Mengyao12,Zhao Yu12ORCID,Xing Guolong12ORCID,Zhu Weidong12ORCID,Ben Teng132ORCID

Affiliation:

1. Zhejiang Engineering Laboratory for Green Syntheses and Applications of Fluorine-Containing Specialty Chemicals, Institute of Advanced Fluorine-Containing Materials, Zhejiang Normal University, Jinhua 321004, P. R. China

2. Key Laboratory of the Ministry of Education for Advanced Catalysis Materials, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua 321004, P. R. China

3. Science and Technology Center for Quantum Biology, National Institute of Extremely-Weak Magnetic Field Infrastructure, Hangzhou 310000, P. R. China

Abstract

The topochemical 1,4-addition reaction of diacetylene was successfully conducted within a three-dimensional diacetylene-containing covalent organic framework under thermal induction for the first time.

Funder

Natural Science Foundation of Zhejiang Province

National Key Research and Development Program of China

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

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