Regio(ir)regular naphthalenediimide- and perylenediimide-bithiophene copolymers: how MO localization controls the bandgap-Reference-Cited by-同舟云学术

Regio(ir)regular naphthalenediimide- and perylenediimide-bithiophene copolymers: how MO localization controls the bandgap

Published:2016 Issue:40 Volume:4 Page:9405-9410
ISSN:2050-7526
Container-title:Journal of Materials Chemistry C
language:en
Short-container-title:J. Mater. Chem. C

Author:

Milián-Medina Begoña¹²³⁴⁵,Wykes Michael⁶⁷⁸⁵,Chen Zhihua⁹¹⁰¹¹,Facchetti Antonio⁹¹⁰¹¹,Gierschner Johannes⁶⁷⁸⁵^ORCID

Affiliation:

1. Department for Physical Chemistry

2. Faculty of Chemistry

3. University of Valencia

4. Valencia

5. Spain

6. Madrid Institute for Advanced Studies

7. IMDEA Nanoscience

8. 28049 Madrid

9. Polyera Corporation

10. Illinois 60077

11. USA

Abstract

Regio-regularity has negligible impact on the optical spectra of naphthalene- and perylene-diimide-bithiophene copolymers (NDI-2T, PDI-2T), due to localized frontier (F-)MOs. In PDI-2T the FMOs are localized in PDI, while in NDI-2T they are largely localized in the respective donor/acceptor units.

Funder

European Commission

Ministerio de Economía y Competitividad

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/TC/C6TC03056D

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