Primary vs. secondary H-atom abstraction in the Cl-atom reaction with n-pentane-Reference-Cited by-同舟云学术

Primary vs. secondary H-atom abstraction in the Cl-atom reaction with n-pentane

Published:2017 Issue:2 Volume:19 Page:1614-1626
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Pandit Shubhrangshu¹²³⁴,Hornung Balázs¹²³⁴,Dunning Greg T.¹²³⁴,Preston Thomas J.¹²³⁴,Brazener Kristian¹²³⁴,Orr-Ewing Andrew J.¹²³⁴^ORCID

Affiliation:

1. School of Chemistry

2. University of Bristol

3. Bristol BS8 1TS

4. UK

Abstract

Velocity map imaging measurements and quasi-classical trajectory calculations on a newly developed, global potential energy surface combine to reveal the detailed mechanisms of reaction of Cl atoms with n-pentane.

Funder

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2017/CP/C6CP07164C

Reference64 articles.

1. Unexpectedly high concentrations of molecular chlorine in coastal air

2. Chlorine as a primary radical: evaluation of methods to understand its role in initiation of oxidative cycles

3. Time-resolved measurements of OH and HO2 product formation in pulsed-photolytic chlorine atom initiated oxidation of neopentane

4. Uncovering the Fundamental Chemistry of Alkyl + O2 Reactions via Measurements of Product Formation

5. Unique isoprene oxidation products demonstrate chlorine atom chemistry occurs in the Houston, Texas urban area

Cited by 8 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Fate of 1,3-dioxolane in the troposphere: kinetics, mechanism with theoretical support, and atmospheric implications;Journal of Atmospheric Chemistry;2023-04-12

2. Impact of the Water Molecule on the Gas-Phase Reaction between Acetone and Cl Atoms;ACS Earth and Space Chemistry;2021-04-02

3. First-Principles Reaction Dynamics beyond Six-Atom Systems;The Journal of Physical Chemistry A;2021-02-25

4. Investigation into reactions of methyl methacrylate and ethyl acrylate with chlorine atom;Chemosphere;2019-04

5. Collision Energy Dependence of the Competing Mechanisms of Reaction of Chlorine Atoms with Propene;The Journal of Physical Chemistry A;2019-03-13