Enantioselective reductive multicomponent coupling reactions between isatins and aldehydes-Reference-Cited by-同舟云学术

Enantioselective reductive multicomponent coupling reactions between isatins and aldehydes

Published:2015 Issue:11 Volume:6 Page:6086-6090
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Horwitz Matthew A.¹²³⁴,Tanaka Naoya⁵⁶⁷⁸⁹,Yokosaka Takuya¹²³⁴,Uraguchi Daisuke⁵⁶⁷⁸⁹,Johnson Jeffrey S.¹²³⁴,Ooi Takashi⁵⁶⁷⁸⁹

Affiliation:

1. Department of Chemistry

2. The University of North Carolina at Chapel Hill

3. Chapel Hill

4. USA

5. Institute of Transformative Bio-Molecules (WPI-ITbM) and Department of Applied Chemistry

6. Graduate School of Engineering

7. Nagoya University

8. Nagoya 464-8602

9. Japan

Abstract

A reductive coupling of two different carbonyls via a polar two-electron reaction mechanism was developed and the stereochemical outcome of this multicomponent process is precisely controlled by a chiral triaminoiminophosphorane.

Funder

Japan Society for the Promotion of Science

Ministry of Education, Culture, Sports, Science, and Technology

National Institute of General Medical Sciences

Core Research for Evolutional Science and Technology, Japan Science and Technology Agency

Nagoya University

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/SC/C5SC02170G

Reference53 articles.

1. A new carbon-carbon condensation via cyclic oxyphosphoranes. Tartaric acids from α-ketoesters

2. Reductive Cross Coupling Reaction of a Glyoxylate with Carbonyl Compounds. A Facile Synthesis of α,β-Dihydroxycarboxylate Based on a Low Valent Titanium Compound

3. Catalytic Redox-Initiated Glycolate Aldol Additions of Silyl Glyoxylates

4. Evolution of the stereoselective pinacol coupling reaction

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