Evidence of protonation induced intra-molecular metal-to-metal charge transfer in a highly symmetric cyanido bridged {Fe2Ni2} molecular square-Reference-Cited by-同舟云学术

Evidence of protonation induced intra-molecular metal-to-metal charge transfer in a highly symmetric cyanido bridged {Fe2Ni2} molecular square

Published:2021 Issue:6 Volume:50 Page:2057-2066
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Mudoi Prashurya Pritam¹²³⁴,Sarma Bipul¹²³⁴^ORCID,Choudhury Anup¹²³⁴,Gogoi Nayanmoni¹²³⁴^ORCID

Affiliation:

1. Department of Chemical Sciences

2. Tezpur University

3. Sonitpur

4. India

Abstract

A highly symmetric cyanido bridged tetranuclear square shaped [NiII2FeIII2] aggregate exhibits protonation induced intra-molecular electron transfer in solution and switching between [NiII2FeIII2] and [NiIII2FeII2] states.

Funder

Science and Engineering Research Board

Tezpur University

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D0DT02826F

Reference72 articles.

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5. Observation of an Fe(II) Spin-Crossover in a Cesium Iron Hexacyanochromate

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