Faster palladium-catalyzed arylation of simple arenes in the presence of a methylketone: beneficial effect of an a priori interfering solvent in C–H activation-Reference-Cited by-同舟云学术

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Faster palladium-catalyzed arylation of simple arenes in the presence of a methylketone: beneficial effect of an a priori interfering solvent in C–H activation

Published:2021 Issue:9 Volume:8 Page:1941-1951
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Salamanca Vanesa¹²³^ORCID,Albéniz Ana C.¹²³^ORCID

Affiliation:

1. IU CINQUIMA/Química Inorgánica. Universidad de Valladolid

2. 47071 Valladolid

3. Spain

Abstract

A methyl ketone accelerates the Pd-catalyzed C–H activation of simple arenes. A noninnocent solvent, it reacts in a reversible way without affecting the outcome of the reaction.

Funder

Consejería de Educación, Junta de Castilla y León

Ministerio de Ciencia e Innovación

Universidad de Valladolid

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/QO/D1QO00236H

Reference71 articles.

1. Palladium-catalyzed direct arylation of simple arenes in synthesis of biaryl molecules

2. Transition-Metal-Catalyzed Direct Arylation of (Hetero)Arenes by Cï£¿H Bond Cleavage

3. Palladium-Catalyzed Ligand-Directed C−H Functionalization Reactions

4. Increasing Catalyst Efficiency in C−H Activation Catalysis

5. Weak Coordination as a Powerful Means for Developing Broadly Useful C–H Functionalization Reactions

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3. Non‐Directed C−H Arylation of Anisole Derivatives via Pd/S,O‐Ligand Catalysis;Angewandte Chemie International Edition;2024-03-28

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