Silver-catalyzed radical ring-opening of cycloalkanols for the synthesis of distal acylphosphine oxides-Reference-Cited by-同舟云学术

Silver-catalyzed radical ring-opening of cycloalkanols for the synthesis of distal acylphosphine oxides

Published:2022 Issue:16 Volume:9 Page:4334-4340
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Li Cheng-Kun¹,Shoberu Adedamola¹,Zou Jian-Ping¹^ORCID

Affiliation:

1. Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry and Chemical Engineering, Soochow University, 199 Renai Street, Suzhou, Jiangsu 215123, China

Abstract

This article reports a novel silver-catalyzed ring-opening approach for the regioselective synthesis of distal acylphosphine oxides; the mechanistic studies reveal the cross-coupling of alkyl and phosphorous-centered radicals.

Funder

National Natural Science Foundation of China

Priority Academic Program Development of Jiangsu Higher Education Institutions

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/QO/D2QO00359G

Reference94 articles.

1. Effective Catalyst for Oxidation Synthesis of 2,4,6-Trimethylbenzoyldipenylphosphine Oxide: V/MCM-41

2. Chlorosilane-Catalyzed Coupling of Hydrogen Phosphine Oxides with Acyl Chlorides Generating Acylphosphine Oxides