N-doped nonalternant aromatic belt <i>via</i> a six-fold annulative double N-arylation-Reference-Cited by-同舟云学术

N-doped nonalternant aromatic belt via a six-fold annulative double N-arylation

Published:2022 Issue:34 Volume:13 Page:9947-9951
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Sato Hiroki¹,Suizu Rie²³^ORCID,Kato Tomoki²,Yagi Akiko¹,Segawa Yasutomo²⁴⁵⁶^ORCID,Awaga Kunio²⁷,Itami Kenichiro¹²⁶⁷^ORCID

Affiliation:

1. Institute of Transformative Bio-Molecules (WPI-ITbM), Nagoya University, Chikusa, Nagoya, 464-8602, Japan

2. Graduate School of Science, Nagoya University, Chikusa, Nagoya, 464-8602, Japan

3. Japan Science and Technology Agency (JST), PRESTO, 4-1-8 Honcho, Kawaguchi, Saitama, 332-0012, Japan

4. Institute for Molecular Science, Myodaiji, Okazaki, 444-8787, Japan

5. Department of Structural Molecular Science, SOKENDAI (The Graduate University for Advanced Studies), Myodaiji, Okazaki, 444-8787, Japan

6. JST-ERATO, Nagoya University, Itami Molecular Nanocarbon Project, Chikusa, Nagoya, 464-8602, Japan

7. Integrated Research Consortium on Chemical Sciences (IRCCS), Nagoya University, Japan

Abstract

Nitrogen-doped nonalternant aromatic belt was synthesized via palladium-catalyzed six-fold annulative double N-arylation reaction. The highly symmetric structure and multistep oxidation behavior of the N-belt were confirmed.

Funder

Japan Society for the Promotion of Science

Exploratory Research for Advanced Technology

Japan Science and Technology Agency

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/SC/D2SC02647C

Reference38 articles.

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