Inducing a pH-dependent conformational response by competitive binding to Zn<sup>2+</sup> of a series of chiral ligands of disparate basicity-Reference-Cited by-同舟云学术

Inducing a pH-dependent conformational response by competitive binding to Zn²⁺ of a series of chiral ligands of disparate basicity

Published:2022 Issue:8 Volume:13 Page:2258-2269
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Wootten Matthew M.¹^ORCID,Le Bailly Bryden A. F.¹,Tshepelevitsh Sofja²^ORCID,Leito Ivo²^ORCID,Clayden Jonathan¹^ORCID

Affiliation:

1. School of Chemistry, University of Bristol, Cantock's Close, Bristol BS8 1TS, UK

2. Institute of Chemistry, University of Tartu, Ravila 14a, Tartu 50411, Estonia

Abstract

A chemical system comprising a series of chiral acids of differing pKa, a metal, and a conformationally labile chromophore responds to pH with a CD spectrum that reports the absolute stereochemistry of the most basic anion in the mixture.

Funder

Engineering and Physical Sciences Research Council

H2020 European Research Council

Eesti Teadusagentuur

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/SC/D1SC06812A

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