WOx/ZrOx functionalised periodic mesoporous organosilicas as water-tolerant catalysts for carboxylic acid esterification

Author:

dos Santos-Durndell Vannia C.1,Durndell Lee J.1ORCID,Isaacs Mark A.23ORCID,Lee Adam F.4,Wilson Karen4ORCID

Affiliation:

1. School of Geography, Earth and Environmental Sciences, Plymouth University, Plymouth, PL4 8AA, UK

2. Department of Chemistry, University College London, London, WC1E 6BT, UK

3. HarwellXPS, Research Complex at Harwell, Rutherford Appleton Laboratory, Didcot, Oxfordshire, OX11 0DE, UK

4. Centre for Advanced Materials and Industrial Chemistry (CAMIC), RMIT University, Melbourne, VIC, 3000, Australia

Abstract

Kicking out water: optimising the interaction between support hydrophobicity and surface acid sites in WOx/ZrOx/PMO catalysts unlocks an efficient route for the upgrading of low-quality waste bio-oil feedstocks to biodiesel.

Funder

Engineering and Physical Sciences Research Council

Royal Society of Chemistry

Conselho Nacional de Desenvolvimento Científico e Tecnológico

Australian Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Energy Engineering and Power Technology,Fuel Technology,Renewable Energy, Sustainability and the Environment

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