Synthesis, crystal structure, electronic structure, and photoelectric response properties of KCu2SbS3-Reference-Cited by-同舟云学术

Synthesis, crystal structure, electronic structure, and photoelectric response properties of KCu2SbS3

Published:2016 Issue:8 Volume:45 Page:3473-3479
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Wang Ruiqi¹²³⁴⁵,Zhang Xian¹²³⁴⁵,He Jianqiao⁶⁷⁸⁹¹⁰,Zheng Chong¹¹¹²¹³¹⁴,Lin Jianhua¹²³⁴⁵,Huang Fuqiang¹²³⁴⁵

Affiliation:

1. Beijing National Laboratory for Molecular Sciences and State Key Laboratory of Rare Earth Materials Chemistry and Applications

2. College of Chemistry and Molecular Engineering

3. Peking University

4. Beijing 100871

5. China

6. CAS Key Laboratory of Materials for Energy Conversion and State Key Laboratory of High Performance Ceramics and Superfine Microstructure

7. Shanghai Institute of Ceramics

8. Chinese Academy of Sciences

9. Shanghai 200050

10. P. R. China

11. Department of Chemistry and Biochemistry

12. Northern Illinois University

13. DeKalb

14. USA

Abstract

A new layered compound KCu₂SbS₃ was synthesized via a facile reactive flux method. The compound, whose crystal structure features [Cu₂SbS₃]⁻ layers packing along [001], possesses a direct-transition band gap of 1.7 eV. Photoelectric measurement demonstrates the potential for applications in photovoltaic devices.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C5DT03910J

Reference47 articles.

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