Rapid one-pot synthesis of pyrrole-appended isocorroles
Author:
Affiliation:
1. Department of Chemistry
2. UiT – The Arctic University of Norway
3. 9037 Tromsø
4. Norway
5. Advanced Light Source
6. Lawrence Berkeley National Laboratory
7. Berkeley
8. USA
Abstract
Free-base meso-triarylcorroles and pyrrole undergo oxidative coupling in dichloromethane in the presence of DDQ affording 35–60% yields of 5/10-pyrrole-appended isocorroles in a matter of seconds.
Funder
Norges Forskningsråd
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2019/OB/C9OB00168A
Reference34 articles.
1. Synthesis of Corroles and Their Heteroanalogs
2. Electronic Structure of Corrole Derivatives: Insights from Molecular Structures, Spectroscopy, Electrochemistry, and Quantum Chemical Calculations
3. Fighting Cancer with Corroles
4. Synthesis and Characterization of Free-Base, Copper, and Nickel Isocorroles
5. Structure and spectroscopic characterization of free base and metal complexes of 5,5-dimethyl-10,15-bis(pentafluorophenyl)isocorrole
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