Nickel – p-block metal mixed chalcogenides based on AuCu3-type fragments: iodine-assisted synthesis as a way of obtaining new structures-Reference-Cited by-同舟云学术

Nickel – p-block metal mixed chalcogenides based on AuCu3-type fragments: iodine-assisted synthesis as a way of obtaining new structures

Published:2020 Issue:42 Volume:49 Page:15081-15094
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Stroganova Ekaterina A.¹²³⁴,Kazakov Sergey M.¹²³⁴,Efimov Nikolay N.⁵⁶³⁴,Khrustalev Victor N.⁷⁸⁹⁴^ORCID,Keilholz Simon¹⁰¹¹¹²¹³¹⁴,Götze Andre¹⁰¹¹¹²¹³¹⁴,Kohlmann Holger¹⁰¹¹¹²¹³¹⁴^ORCID,Kuznetsov Alexey N.¹²³⁴⁵^ORCID

Affiliation:

1. Department of Chemistry

2. Lomonosov Moscow State University

3. 119991 Moscow

4. Russian Federation

5. N.S. Kurnakov Institute of General and Inorganic Chemistry

6. RAS

7. Joint Institute for Chemical Research

8. RUDN University

9. 117198 Moscow

10. Inorganic Chemistry

11. Faculty for Chemistry and Mineralogy

12. Leipzig University

13. 04103 Leipzig

14. Germany

Abstract

Three new mixed nickel-rich chalcogenides, Ni_9.39Ga₂S₂, Ni_5.80GaTe₂, and Ni_5.78InTe₂, have been synthesized by a high-temperature route with the addition of iodine, and characterized by X-ray diffraction, DFT calculations, and magnetic measurements.

Funder

Russian Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/DT/D0DT03082A

Reference34 articles.

1. Synthesis and Properties of a New Metal-Rich Nickel Antimonide Telluride or Selenide: Ni7-δSbX2 (δ ≈ 1.3; X = Se or Te)

2. New Metal-Rich Sulfides Ni6SnS2 and Ni9Sn2S2 with a 2D Metal Framework: Synthesis, Crystal Structure, and Bonding

3. 2D metal slabs in new nickel–tin chalcogenides Ni7−δSnQ2 (QSe, Te): average crystal and electronic structures, chemical bonding and physical properties