Iodoarene-directed photoredox β-C(sp3)–H arylation of 1-(o-iodoaryl)alkan-1-ones with cyanoarenes via halogen atom transfer and hydrogen atom transfer

Author:

Zeng Liang12,Xu Chong-Hui1,Zou Xiu-Yuan2ORCID,Sun Qing2ORCID,Hu Ming12,Ouyang Xuan-Hui2ORCID,He De-Liang1ORCID,Li Jin-Heng1345ORCID

Affiliation:

1. State Key Laboratory of Chemo/Biosensing and Chemometrics, Hunan University, Changsha 410082, China

2. Key Laboratory of Jiangxi Province for Persistent Pollutants Control and Resources Recycle, Nanchang Hangkong University, Nanchang 330063, China

3. State Key Laboratory Base of Eco-Chemical Engineering, College of Chemical Engineering, Qingdao University of Science and Technology, Qingdao 266042, China

4. State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000, China

5. School of Chemistry and Chemical Engineering, Henan Normal University, Xinxiang, Henan 475004, China

Abstract

Radical-mediated direct photoredox β-C(sp3)–H arylation of 1-(o-iodoaryl)alkan-1-ones with cyanoarenes directed by an iodoarene group is depicted.

Funder

National Natural Science Foundation of China

Henan Normal University

Foundation of Jiangxi Educational Commission

Publisher

Royal Society of Chemistry (RSC)

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